Wear of thermoplastics determined by multiple scratching

M. D. Bermudez (a), W. Brostow (b), F. J. Carrion-Vilches (a, b) J. J. Cervantes (a) and D. Pietkiewicz (b)

(a) Grupo de Ciencia de Materials en Ingenieria Metalurgica, Departamento de Ingenieria de Materiales y Fabricacion, Universidad Politecnica de Cartagena. C/Doctor Fleming s/n, 30302 Cartagena, Spain
(b) Laboratory of Advanced Polymers and Optimized Materials (LAPOM), Department of Materials Science, University of North Texas, Denton, TX 76203-5310, USA

ABSTRACT

We studied wear resistance in sliding by multiple scratching along the same groove for a variety of thermoplastics: polystyrene, styrene-acrylonitrile. poly­amide 6 and polysulfone. Constant-load experiments were carried out with a micro scratch tester for several loads between 2.5 and 15 N: each time 15 scratches were performed. Except for polystyrene, all materials show an asymptotic residual depth as a function of the number of scratch tests performed. In contrast to other materials, polystyrene exhibits brittleness and debris formation. Scanning electron microscopy and scanning probe microscopy were used to characterize the defor­mation and wear mechanisms and were connected to the wear data obtained by multiple scratching. At 15 N we found a viscoelastic recovery for polystyrene of 27.8% while for polyamide 6 the corresponding value is 80.2%.

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